采用闽南、闽北和广东乌龙茶为样本,进行了基于化学成分、因子分析和判别分析的茶样品质评定和产品判别模型研究。应用因子分析得出累积变异量为85.041%的7个公共因子,再以公共因子为自变量,采用同步判别分析法对茶样进行产地、品种和级别鉴别,建立判别函数;交叉验证和回代样本验证结果显示,产地和品种的判别模型正确区别度较高,产地的回代和交叉验证总正判率分别为97.6%和94.0%,品种的为86.9%和75.0%。并确立7个乌龙茶品质因子得分函数和1个综合评价函数,得到判别效果良好的产地判别函数3条、品种判别函数6条。
The model of quality evaluation and products discrimination of Oolong tea based on chemical composition, factor and discriminant analysis were studied with Guangdong, southern and northern Fujian Oolong tea as the samples. Seven factors with cumulative variance of 85.041% were obtained along with factor analysis, set the factors as the independent variable, and discriminating classification of the samples area,variety and grade use discriminant analysis. Then the discrimination functions were established. Results of cross-validation and resubstitution of testing samples demonstrated the correct rates of discrimination model of area and variety was satisfactory. Recognition accuracy of the resubstitution and cross-validation of area were 97.6% and 94.0%, which of variety was 86.9% and 75.0%. Seven score function of quality factor and one comprehensive evaluation function were established for Oolong tea, and three discrimination functions for producing area and six of variety were obtained and the discrimination results were satisfactory.
[1] 夏怡凡. SPSS统计分析精要与实例详解[M]. 北京: 电子工业出版社, 2010: 218-218, 243-244.
[2] 杨红, 汪志君. 茶汤冷后浑中生化成分含量的因子分析[J]. 食品研究与开发, 2006, 27(8): 72-75.
[3] 周利兵. 我国六大名茶中微量元素的评价研究[J]. 湖南农业科学, 2010(13): 123-124, 128.
[4] 成浩, 王丽鸳, 周健, 等. 基于化学指纹图谱的扁形茶产地判别分析研究[J]. 茶叶科学, 2008, 28(2): 83-88.
[5] 叶国注, 袁海波, 江用文, 等. Bayes逐步判别法在绿茶板栗香化学识别上的应用[J]. 茶叶科学, 2009, 29(1): 27-33.
[6] 王丽鸳, 成浩, 周健, 等. 基于多元化学指纹图谱的武夷岩茶身份判别研究[J]. 茶叶科学, 2009, 30(2): 83-88.
[7] Quansheng Chen, Jiewen Zhao, C H Fang, et al. Feasibility study on identification of green, black and Oolong teas using near-infrared reflectance spectroscopy based on support vector machine (SVM)[J]. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2007, 66(3): 568-574.
[8] D Cozzolino, E Restaino, A Fassio.Discrimination of yerba mate (Ilex paraguayensis St. Hil.) samples according to their geographical origin by means of near infrared spectroscopy and multivariate analysis[J]. Sens & Instrumen Food Qual, 2010, 4(2): 67-72.
[9] 董青华. 基于国际标准的乌龙茶理化成分研究[D]. 福州: 福建农林大学, 2010: 47-64.