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儿茶素的碱缓冲能力及与Al3+络合作用的研究

  • 唐德松 ,
  • 沈生荣
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  • 浙江大学茶学系,浙江 杭州 310029
唐德松(1976- ),男,浙江大学茶学系研究生,主要从事茶叶综合利用和生物化学的研究。

收稿日期: 2002-12-19

  修回日期: 2003-03-17

  网络出版日期: 2019-09-16

Study on Catechins’ Buffer Abilities to OH and Their Complex with Al3+

  • TANG De-song ,
  • SHEN Sheng-rong
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  • Teascience department, Zhejiang University. Hangzhou, 310029

Received date: 2002-12-19

  Revised date: 2003-03-17

  Online published: 2019-09-16

摘要

研究了三种儿茶素((+)-C,(–)-EC,EGCG)对碱的缓冲能力,Al3+对儿茶素缓冲能力的影响及EGCG与Al3+的络合作用。结果表明,儿茶素溶液对碱有较强的缓冲能力,酯型儿茶素更强,EGCG约是EC或者C的两倍;在儿茶素与Al3+络合过程中,儿茶素的紫外–可见吸收在274βnm处逐渐下降,而322βnm处逐渐升高;EGCG与Al3+的络合度为1:1。

关键词: 茶学; 儿茶素; Al3+; 缓冲能力

本文引用格式

唐德松 , 沈生荣 . 儿茶素的碱缓冲能力及与Al3+络合作用的研究[J]. 茶叶科学, 2003 , 23(1) : 66 -70 . DOI: 10.13305/j.cnki.jts.2003.01.014

Abstract

In this paper, reactions of catechins chelating with Al3+ were studied. The results showed that, catechins have strong buffer abilities to OH, and EGCG’s is stronger than that of E or EC, After adding Al3+ to catechin solution, its pH value decreased and absorbance at 274βnm went down and at 322βnm went up. The ratio of EGCG-Al in the complex is 1:1.

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