A residue analysis method for thiamethoxam and lambda-cyhalothrin in tea infusion was established, and the influence of brewing time, brewing temperature, tea shape and residue concentration in made tea to the brewing behavior from made tea to tea infusion were investigated by this method. The results showed that: when constant temperature of 100℃ for different brewing time (5~30βmin), the brewing rate of thiamethoxam were maximum at 15βmin, which were 81.2% in whole leaf tea and 88.6% in broken tea, the brewing rate of lambda-cyhalothrin reached the maximum of 5.5% at 25βmin in broken tea, and the whole leaf tea for 0.41%; after brewing in different temperature for 15 min, the brewing rates of thiamethoxam and lambda-cyhalothrin were increased according to the brewing temperature, when the temperature was 100℃, in the whole leaf tea and in the broken tea, the brewing rates of thiamethoxam were the maximum at 83.9% and 89.1%, respectively; and for lambda-cyhalothrin were the maximum at 0.55% and 4.1%, respectively. When constant temperature at 100℃, after brewing 15 min for three times, the brewing rates of two pesticides were decreased with the brewing times, and the total maximum brewing rates of thiamethoxam and lambda-cyhalothrin were at 93.25% and 1.94%, respectively. The extracting concentration of thiamethoxam in tea infusion from made tea were meeting the linear relationship, the equation was Y=0.9267X-0.0336, R2=0.9945, and the concentration of lambda-cyhalothrin in tea infusion extracting from made tea were meeting the quadratic function relationship, the equation was Y=0.0026X2-0.0023X+0.0096, R2=0.9765. On the basis of research, the risk assessment on thiamethoxam and lambda-cyhalothrin in tea during drinking showed that the risk to human health via tea drinking was very small.
ZHANG Fen
,
ZHANG Xin-zhong
,
CHEN Zong-mao
,
LUO Feng-jian
,
LOU Zheng-yun
,
SUN Wei-jiang
. Study on the Brewing Behavior of Two Kinds of Different Solubility Pesticide from Made Tea to Tea Infusion[J]. Journal of Tea Science, 2013
, 33(5)
: 482
-490
.
DOI: 10.13305/j.cnki.jts.2013.05.007
[1] 夏会龙, 王运浩, 王海滨, 等. 茶树生长稀释在农药降解中的定量[J]. 茶叶科学, 1992, 12(2): 1-6.
[2] 孙威江, 林智, 杨享栋. 无公害茶叶[M]. 北京: 中国农业大学出版社. 2001: 93.
[3] Gupta M, Shanker A.Persistence of acetamiprid in tea and its transfer from made tea to infusion[J]. Food Chemistry, 2006, 111(4): 805-810.
[4] Ozbey A, Uygun U.Behaviour of some organophosphorus pesticide residues in thyme and stinging nettle tea during infusion process[J]. Food Chemistry, 2007, 104(1): 237-241.
[5] Barooa A K, Borthakur M, Kalita J N, et al. Pesticide Residues in Tea and Their Intake Assessment Using Brew Factor[J]. Journal of Tea Science, 2011, 31(5): 419-426.
[6] Tewary D K, Kumar V, Ravindranath S D, et al. Dissipation behavior of bifenthrin residues in tea and its brew[J]. Food Control, 2005, 16(3): 231-237.
[7] 王军, 龚勇, 温家钧. 苯醚甲环唑在茶汤中浸出浓度及浸出率的影响因素[J]. 西北农业学报, 2011, 20(2): 202-206.
[8] 张芬, 张新忠, 罗逢健, 等. QuEChERS净化GC/ECD测定茶叶与土壤中的噻虫嗪、虫螨腈及高效氯氟氰菊酯残留[J]. 分析测试学报, 2013, 32(4): 393-400.
[9] 谢文, 钱艳, 丁慧瑛, 等. 液相色谱-电喷雾电离三重四极杆质谱法测定茶叶中6种烟碱类农药残留[J]. 分析化学, 2009, 37(4): 495-499.
[10] 莫小荣, 郑春慧, 陈建伟, 等. 浊点萃取-异辛烷反萃取-气相色谱测定茶叶中拟除虫菊酯农药残留[J]. 分析化学, 2009, 37(8): 1178-1182.
[11] 吴雪原, 盛旋, 樊玮, 等. 三种农药在茶汤中的浸出及对人体健康影响的风险评估[J]. 茶叶科学, 2007, 27(2): 141-146.
[12] 龚淑英, 鲁成银, 刘栩, 等. GB/T 23776—2009 茶叶感官评审方法[S]. 北京: 中国标准出版社. 2009: 1-15.
[13] 罗逢健, 刘光明, 汤富彬, 等. 茶叶中农药残留检测技术应用实例[J]. 中国茶叶, 2008, 30(2): 14-16.
[14] P J Mann-Web Design & Consultancy. The e-Pesticide Manual V. 5.0[EB]. Britain, British Crop Production Council, 2010.
[15] 张新忠, 罗逢健, 陈宗懋, 等. 分散固相萃取净化超高液相色谱串联质谱法研究茶叶和茶汤中茚虫威降解规律[J]. 分析测试学报, 2013, 32(1): 1-8.
[16] 中华人民共和国卫生部, 中华人民共和国农业部. GB 2763—2012 食品安全国家标准食品中农药最大残留限量[S]. 北京: 中国标准出版社. 2013: 72, 90.
[17] 农药电子手册. The e-Pesticide Manual, Version 5.0. Publisher BCPC. 2010.