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茶叶多糖铁的合成及其铁含量的测定

  • 李玉贤 ,
  • 裴晓红
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  • 1. 河南中医学院中药系,河南 郑州450008;
    2. 平顶山市环境监测中心站,河南 平顶山 467000
李玉贤(1963— ),女,副教授,主要从事天然产物化学研究。

网络出版日期: 2019-09-16

Synthesis of tea polysaccharide-Fe(Ⅲ)complex and determination of Fe(Ⅲ)

  • LI Yu-xian ,
  • PEI Xiao-hong
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  • 1. Department of Chinese Medicine, Henan College of Traditional Chinese Medicine, Zhengzhou 450008, China;
    2. Pingdingshan Environmental monitoring station, Pingdingshan 467000, China

Online published: 2019-09-16

摘要

用热水浸泡法从粗老茶叶中提取茶叶多糖,在碱性条件下,茶叶多糖水溶液与三氯化铁反应合成茶叶多糖铁配合物(TPC),并用邻菲罗啉分光光度法和原子吸收光谱法测定TPC中铁(Ⅲ)的含量。实验结果表明:TPC是深棕红色无定型粉末, 易溶于水,在pH值3~12范围内不沉淀,不水解。TPC中铁(Ⅲ)的含量:邻菲罗啉分光光度法测定结果为20.71%,原子吸收光谱法测定结果为20.13%。

本文引用格式

李玉贤 , 裴晓红 . 茶叶多糖铁的合成及其铁含量的测定[J]. 茶叶科学, 2005 , 25(1) : 71 -74 . DOI: 10.13305/j.cnki.jts.2005.01.013

Abstract

Tea polysaccharide was abstracted with warm water, tea polysaccharide-Fe(Ⅲ)complex(TPC) was synthesized with tea polysaccharide and FeCl3 under the alkaline condition, The determination of Fe(Ⅲ) was conducted with the method of ferroin-Fe(Ⅱ) and atomic absorption spectrophometry. The results showed that: TPC is heavy brownish red and shapeless powder. It can dissolve in water, its solution is very stable at the pH from 3 to 12. Content of Fe(Ⅲ)in TPC is 20.71% by the method of ferroin- Fe(Ⅱ)and 20.13% by the method of atomic absorption.

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