茶渣基摩擦纳米发电机的性能优化及风力监测系统应用研究

doi:10.13305/j.cnki.jts.2025.01.010

摘要/Abstract

摘要： 研制了一种新型茶渣基摩擦纳米发电机（Tea residue powder based triboelectric nanogenerator,TRP-TENG）,并以其为基础开发了智慧风力监测装置。以不同发酵程度的茶渣超微粉末作为摩擦膜材料,制备了不同的摩擦纳米发电机,通过水平往复冲压平台测试比较其电输出性能差异,寻找TRP-TENG的最佳材料并进行器件的优化。进一步对优化后的TRP-TENG进行频率响应、负载特性、可持续性和供电能力等方面的测试和分析,评估其在风力监测装置中的应用可行性。试验结果表明,以白茶茶渣作为材料开发的TRP-TENG电输出性能最优,其开路电压和短路电流分别可达9.1 V和4.4 µA,且具备一定的稳定性;白茶茶渣的茶多酚、儿茶素组分含量较高,茶色素含量较低,对应的TRP膜具有疏松多孔的凹凸表面微结构,能够有效增加接触面积,有助于提高TENG的电输出性能。该TRP-TENG可以适应多种振动频率工作环境,并且在外接电阻为50 MΩ时,电输出功率达108.0 µW;在驱动频率为3 Hz时,可同时点亮5颗串联的商业LED灯,在10 µF的电容充电5 min后,能使电子计时器连续工作15 s。以4个串联的TRP-TENG为基础部件开发的自供能风力监测装置对风速具有较明显的响应灵敏度,可适用于智慧农业系统。

关键词: 茶渣, 摩擦纳米发电机, 能源收集, 自供能传感器, 智慧农业

Abstract: A new type of tea residue powder based triboelectric nanogenerator (TRP-TENG) was developed, and a smart wind monitoring device was developed based on it. During the experimental process, tea residue ultrafine powders with different degrees of fermentation were used as friction film materials to prepare different triboelectric nanogenerators. The differences in electrical output performance were tested and compared on a horizontal reciprocating stamping platform to find the optimal material for TRP-TENG and to optimize the device. On this basis, further testing and analysis were conducted on the optimized TRP-TENG in terms of frequency response, load characteristics, sustainability, and power supply capacity to evaluate its feasibility for application in wind monitoring devices. The experimental results show that the TRP-TENG developed with white tea residue as the material had the best electrical output performance, with an open-circuit voltage and short-circuit current of 9.1 V and 4.4 µA, respectively, and had a certain degree of stability. The contents of tea polyphenols and catechins in white tea residue were relatively high, while the contents of tea pigments were low. The corresponding TRP film had a loose and porous concave-convex surface microstructure, which could effectively increase the contact area and help improve the electrical output performance of TENG. This TRP-TENG could adapt to various vibration frequency working environments, and when the external resistance was 50 MΩ, the electrical output power reached 108.0 µW. At a driving frequency of 3 Hz, it could simultaneously light up 5 series connected commercial LED lights, and it could make the electronic timer work continuously for 15 s after charging the 10 µF capacitor for 5 min. In terms of application, a self-powered wind monitoring device was developed based on four series of connected TRP-TENG components. The test results show that this device has a significant response sensitivity to wind speed and can be applied to smart agriculture systems.

Key words: tea residue, triboelectric nanogenerator, energy collection, self-powered sensor, smart agriculture

中图分类号:

林东艺, 黄冲, 王未名, 黄艳, 冯新凯. 茶渣基摩擦纳米发电机的性能优化及风力监测系统应用研究[J]. 茶叶科学, 2025, 45(1): 121-132. doi: 10.13305/j.cnki.jts.2025.01.010.

LIN Dongyi, HUANG Chong, WANG Weiming, HUANG Yan, FENG Xinkai. Research on Performance Optimization of Tea Residue Powder-Based Triboelectric Nanogenerator and It’s Application in Wind Monitoring System[J]. Journal of Tea Science, 2025, 45(1): 121-132. doi: 10.13305/j.cnki.jts.2025.01.010.

参考文献

[1] 林晓鹏, 顾天平. 物联网技术在现代农业中的应用概况[J]. 农业工程技术, 2024, 44(5): 84-85.
Lin X P, Gu T P.Overview of the application of internet of things technology in modern agriculture[J]. Agricultural Engineering Technology, 2024, 44(5): 84-85.
[2] 王未名, 林东艺, 王丹海, 等. 废弃茶叶基摩擦纳米发电机开发及其应用[J]. 宁德师范学院学报(自然科学版), 2024, 36(1): 92-98.
Wang W M, Lin D Y, Wang D H, et al.Development and application of triboelectric nanogenerator based on waste tea[J]. Journal of Ningde Normal University (Natural Science), 2024, 36(1): 92-98.
[3] 阚君武, 吕鹏, 王进, 等. 脱涡致振式压电风力发电机性能分析与试验[J]. 农业机械学报, 2021, 52(4): 411-417.
Kan J W, Lü P, Wang J, et al.Performance analysis and test of vortex induced vibration piezoelectric wind harvester[J]. Transactions of the Chinese Society for Agricultural Machinery, 2021, 52(4): 411-417.
[4] 杨鹏, 耿正龙, 张永磊, 等. 风光互补发电系统在转地饲养蜂场中的应用研究[J]. 中国农业科技导报, 2017, 19(8): 71-76.
Yang P, Geng Z L, Zhang Y L, et al.Application and research on wind-solar hybrid generation system in different feeding apiary[J]. Journal of Agricultural Science and Technology, 2017, 19(8): 71-76.
[5] Fan F R, Tian Z Q, Wang Z L.Flexible triboelectric generator[J]. Nano Energy, 2012, 1(2): 328-334.
[6] Ren Z W, Wu L T, Pang Y K, et al.Strategies for effectively harvesting wind energy based on triboelectric nanogenerators[J]. Nano Energy, 2022, 100: 107522. doi: 10.1016/j.nanoen.2022.107522.
[7] Shi B R, Wang Q M, Su H, et al.Progress in recent research on the design and use of triboelectric nanogenerators for harvesting wind energy[J]. Nano Energy, 2023, 116: 108789. doi: 10.1016/j.nanoen.2023.108789.
[8] Hu Y X, Li X Y, Gao Y K, et al.A combined wind harvesting and speed sensing system based on constant-voltage triboelectric nanogenerator[J]. Advanced Energy Materials, 2024, 14(23): 2400672. doi: 10.1002/aenm.202400672.
[9] Saqib Q M, Shaukat R A, Khan M U, et al.Biowaste peanut shell powder-based triboelectric nanogenerator for biomechanical energy scavenging and sustainably powering electronic supplies[J]. ACS Applied Electronic Materials, 2020, 2(12): 3953-3963.
[10] Wang S, Lin L, Wang Z L.Triboelectric nanogenerators as self-powered active sensors[J]. Nano Energy, 2015, 11: 436-462.
[11] Zheng Q, Tang Q, Wang Z L, et al.Self-powered cardiovascular electronic devices and systems[J]. Nature Reviews Cardiology, 2021, 18(1): 7-21.
[12] Li H, Zhao C C, Wang X X, et al.Fully bioabsorbable capacitor as an energy storage unit for implantable medical electronics[J]. Advanced Science, 2019, 6(6): 1801625. doi: 10.1002/advs.201801625.
[13] Li Z, Feng H Q, Zheng Q, et al.Photothermally tunable biodegradation of implantable triboelectric nanogenerators for tissue repairing[J]. Nano Energy, 2018, 54: 390-399.
[14] Choi D, Yoo D, Cha K J, et al.Spontaneous occurrence of liquid-solid contact electrification in nature: toward a robust triboelectric nanogenerator inspired by the natural lotus leaf[J]. Nano Energy, 2017, 36: 250-259.
[15] Zhang R Y, Hummelgård M, Örtegren J, et al.High performance single material-based triboelectric nanogenerators made of hetero-triboelectric half-cell plant skins[J]. Nano Energy, 2022, 94: 106959. doi: 10.1016/j.nanoen.2022.106959.
[16] Alluri N R, Raj N P M J, Khandelwal G, et al. Aloe vera: a tropical desert plant to harness the mechanical energy by triboelectric and piezoelectric approaches[J]. Nano Energy, 2020, 73: 104767. doi: 10.1016/j.nanoen.2020.104767.
[17] Wu J M, Chang C K, Chang Y T.High-output current density of the triboelectric nanogenerator made from recycling rice husks[J]. Nano Energy, 2016, 19: 39-47.
[18] Jiao J Y, Lu Q X, Wang Z L, et al.Sandwich as a triboelectric nanogenerator[J]. Nano Energy, 2021, 79: 105411. doi: 10.1016/j.nanoen.2020.105411.
[19] Saqib Q M, Shaukat R A, Khan M U, et al.Biowaste peanut shell powder-based triboelectric nanogenerator for biomechanical energy scavenging and sustainably powering electronic supplies[J]. ACS Applied Electronic Materials, 2020, 2(12): 3953-3963.
[20] Xia K Q, Zhu Z Y, Fu J M, et al.A triboelectric nanogenerator based on waste tea leaves and packaging bags for powering electronic office supplies and behavior monitoring[J]. Nano Energy, 2019, 60: 61-71.
[21] Zhu H K, Liu F, Ye Y, et al.Application of machine learning algorithms in quality assurance of fermentation process of black tea: based on electrical properties[J]. Journal of Food Engineering, 2019, 263: 165-172.
[22] 冯呈艳, 余志, 陈玉琼, 等. 茶鲜叶介电特性的初步研究[J]. 华中农业大学学报, 2014, 33(2): 111-115.
Feng C Y, Yu Z, Chen Y Q, et al.Researches on the dielectric property of fresh tea leaves[J]. Journal of Huazhong Agricultural University, 2014, 33(2): 111-115.
[23] Hua J J, Xu Q, Yuan H B, et al.Effects of novel fermentation method on the biochemical components change and quality formation of Congou black tea[J]. Journal of Food Composition and Analysis, 2021, 96: 103751. doi: 10.1016/j.jfca.2020.103751.
[24] 蒋阿婷, 刘巧芳, 肖娟娟, 等. 湖南黑毛茶优化拼配样的风味品质研究[J]. 茶叶科学, 2024, 44(5): 763-778.
Jiang A T, Liu Q F, Xiao J J, et al.Research on flavors and qualities of optimization blending samples of Hunan raw dark teas[J]. Journal of Tea Science, 2024, 44(5): 763-778.
[25] Dudem B, Dharmasena R D I G, Graham S A, et al. Exploring the theoretical and experimental optimization of high-performance triboelectric nanogenerators using microarchitectured silk cocoon films[J]. Nano Energy, 2020, 74: 104882. doi: 10.1016/j.nanoen.2020.104882.
[26] Diaz A F, Felix-Navarro R M. A semi-quantitative tribo-electric series for polymeric materials: the influence of chemical structure and properties[J]. Journal of Electrostatics, 2004, 62(4): 277-290.
[27] 王盛琳, 杨崇山, 刘中原, 等. 基于电特性的红茶发酵中茶多酚含量快速检测方法[J]. 茶叶科学, 2021, 41(2): 251-260.
Wang S L, Yang C S, Liu Z Y, et al.Rapid detection method of tea polyphenol content in black tea fermentation based on electrical properties[J]. Journal of Tea Science, 2021, 41(2): 251-260.
[28] 张宁, 何剑, 丑修建. PDMS基摩擦纳米发电机膜内掺杂[J]. 微纳电子技术, 2021, 58(4): 309-315.
Zhang N, He J, Chou X J.Intramembrane doping of PDMS-based triboelectric nanogenerator[J]. Micronanoelectronic Technology, 2021, 58(4): 309-315.