MWCNTs-IL-SPCE传感器检测茶叶中痕量铅研究

doi:10.13305/j.cnki.jts.2011.06.002

茶叶科学 ›› 2011, Vol. 31 ›› Issue (6): 485-492.doi: 10.13305/j.cnki.jts.2011.06.002

MWCNTs-IL-SPCE传感器检测茶叶中痕量铅研究

徐旭明, 窦文超, 赵广英^*

浙江工商大学食品与生物工程学院,浙江省食品安全重点实验室,浙江杭州 310035

收稿日期:2011-03-14 修回日期:2011-07-18 出版日期:2011-12-15 发布日期:2019-09-09
通讯作者: zhaogy-user@163.com
作者简介:徐旭明（1986— ）,男,浙江建德人,硕士研究生,主要从事电化学检测重金属的研究。
基金资助:
国家自然科学基金(No.30571623)、浙江省重中之重学科(No.Z05-29)、浙江工商大学校级创新基金(No.1110XJ1710139)、浙江工商大学新苗人才项目（No.3070JQ4111087G）

Multi-walled Carbon Nanotubes-Ionic Liquid Modified Screen-printed Carbon Electrodes for the Determination of Trace Lead in Tea

XU Xu-ming, DOU Wen-chao, ZHAO Guang-ying^*

Food safety lab of Zhejiang Province, College of Food Science and Biotechnology Engineering, Zhejiang Gongshang University, Hangzhou 310035, China

Received:2011-03-14 Revised:2011-07-18 Online:2011-12-15 Published:2019-09-09

摘要/Abstract

摘要： 研究构建了一种新型、高灵敏性和高选择性的电化学传感器,结合差分脉冲溶出伏安法快速检测茶叶样品中的痕量铅。采用超传导性粘结剂离子液体1-丁基-3-甲基咪唑六氟磷酸盐（[BMIM]PF₆）和功能化的多壁碳纳米管（MWCNTs）修饰丝网印刷碳电极,提高了电极表面的导电性和信号转换。在含0.006mol/L I^–, pH4.5的NaAc-HAc缓冲液中,Pb²⁺在–1.1V沉积电位下吸附于MWCNTs-IL-SPCE膜上,当正电压扫过时,铅氧化溶出,在–0.30V下出现一个很好的溶出峰,低浓度的I¯明显增强了铅的溶出峰电流。溶出峰高值与Pb²⁺浓度在2~600μg/L范围内呈线性关系,相关系数为0.99926,检测限为0.63μg/L。试验结果与ICP-MS测定值进行t检验,无显著性差异。该方法灵敏、稳定,可用于茶叶中痕量铅简单、经济的检测。

关键词: 多壁碳纳米管, 离子液体, 丝网印刷碳电极, 茶叶, 铅

Abstract: A new, high sensitivity and selectivity electrochemical sensor for determination of trace lead in tea by differential pulse stripping voltammetry was investigated. For modification of the screen-printed carbon electrode, 1-butyl-3-methylimidazolium hexafluorophosphate was applied as a super conductive binder and multi-walled carbon nanotubes were used after being functionalized. They improved the conductivity and signal transduction of electrode surface. In pH4.5 NaAc-HAc buffer containing 0.006mol/L I^¯, Pb²⁺ adsorbed onto the surface of MWCNTs-IL film coated SPCE at the deposition potential of –1.1V. During the positive potential sweep, lead was oxidized, and a good stripping peak appeared at –0.30V. Low concentration of I^¯ significantly enhanced the stripping peak current of lead. The liner relationship between stripping peak value and concentration of Pb²⁺ was in the range of 2~600μg/L with the R value of 0.99926 and detection limit of 0.63μg/L. No significant difference existed after the detection results were compared with ICP-MS method using t test. The high sensitivity and stability of this method demonstrated the application for a simple and economical determination of trace lead in tea.

Key words: multi-walled carbon nanotubes, ionic liquid, screen-printed carbon electrode, tea, lead

中图分类号:

TS272
Q493.7

徐旭明, 窦文超, 赵广英. MWCNTs-IL-SPCE传感器检测茶叶中痕量铅研究[J]. 茶叶科学, 2011, 31(6): 485-492. doi: 10.13305/j.cnki.jts.2011.06.002.

XU Xu-ming, DOU Wen-chao, ZHAO Guang-ying. Multi-walled Carbon Nanotubes-Ionic Liquid Modified Screen-printed Carbon Electrodes for the Determination of Trace Lead in Tea[J]. Journal of Tea Science, 2011, 31(6): 485-492. doi: 10.13305/j.cnki.jts.2011.06.002.

参考文献

[1] Chung FL, Schwartz J, Herzog CR, et al. Tea and cancer prevention: studies in animals and humans[J]. The Journal of Nutrition, 2003(133): 3268S-3274S.
[2] Hirano R, Momiyama Y, Takahashi R, et al. Comparison of green tea intake in Japanese patients with and without angiographic coronary artery disease[J]. The American Journal of Cardiology, 2002(90): 1150-1153.
[3] Yang CS, Chung JY, Yang GY, et al. Tea and tea polyphenols in cancer prevention[J]. The Journal of Nutrition, 2000(130): 472S-478S.
[4] Jin CW, Zheng SJ, He YF, et al. Lead contamination in tea garden soils and factors affecting its bioavailability[J]. Chemosphere, 2005(59): 1151-1159.
[5] Jin CW, He YF, Zhang K, et al. Lead contamination in tea leaves and non-edaphic factors affecting it[J]. Chemosphere, 2005(61): 726-732.
[6] 石元值, 马立峰, 韩文炎, 等. 浙江省茶园中铅元素含量现状研究[J]. 茶叶科学, 2003, 23(2): 163-166.
[7] Han WY, Zhao FJ, Shi YZ, et al. Scale and causes of lead contamination in Chinese tea[J]. Environmental Pollution, 2006(139): 125-132.
[8] Gunasingham H, Dalangin RR.Anodic stripping voltammetry of lead using a copper-mercury film electrode[J]. Analytica Chimica Acta, 1991(246): 309-313.
[9] Zen JM, Huang SY.Square-wave voltammetric determination of lead(Ⅱ) with a Nafion/2,2-bipyridyl mercury film electrode[J]. Analytica Chimica Acta, 1994(296): 77-86.
[10] Carapuca HM, Monterroso SCC, Rocha LS, et al. Simultaneous determination of copper and lead in seawater using optimised thin-mercury film electrodes in situ plated in thiocyanate media[J]. Talanta, 2004(64): 566-569.
[11] Ghiaci M, Rezaei B, Kalbasi RJ.High selective SiO₂-Al₂O₃ mixed-oxide modified carbon paste electrode for anodic stripping voltammetric determination of Pb[J]. Talanta, 2007(73): 37-45.
[12] Somerset V, Iwuoha E, Hernandez L.Stripping voltammetric measurement of trace metal ions at screen-printed carbon and carbon paste electrodes[J]. Procedia Chemistry, 2009(1): 1279-1282.
[13] Senthilkumar S, Saraswathi R.Electrochemical sensing of cadmium and lead ions at zeolite-modified electrodes: optimization and field measurements[J]. Sensors and Actuators B, 2009(141): 65-75.
[14] El Mhammedi MA, Achak M, Chtaini A.Ca₁₀(PO₄)₆, 2009(161): 55-61.
[15] Rao GP, Lu C, Su F.Sorption of divalent metal ions from aqueous solution by carbon nanotubes: A review[J]. Separation and Purification Technology, 2007(58): 224-231.
[16] Rozniecka E, Shul G, Sirieix-Plenet J, et al. Electroactive ceramic carbon electrode modified with ionic liquid[J]. Electrochemistry Communications, 2005(7): 299-304.
[17] Khani H, Rofouei MK, Arab P, et al. Multi-walled carbon nanotubes-ionic liquid-carbon paste electrode as a super selectivity sensor: Application to potentiometric monitoring of mercury ion[J]. Journal of Hazardous Materials, 2010(183): 402-409.
[18] Wu K, Hu S, Fei J, et al. Mercury-free simultaneous determination of cadmium and lead at a glassy carbon electrode modified with multi-wall carbon nanotubes[J]. Analytica Chimica Acta, 2003(489): 215-221.
[19] 梁逸曾, 俞汝勤. 化学计量学[M]. 北京: 高等教育出版社, 2003: 116-185.
[20] 张虹. 加标回收率的测定和结果判断[J]. 石油与天然气化工, 2000, 29(1): 50-52.

MWCNTs-IL-SPCE传感器检测茶叶中痕量铅研究

Multi-walled Carbon Nanotubes-Ionic Liquid Modified Screen-printed Carbon Electrodes for the Determination of Trace Lead in Tea

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